Broadband and adiabatic inversion of a two-level system by phase-modulated pulses.

We describe a class of continuously phase-modulated radiation pulses that result in coherent population inversion on resonance as well as over a large range of transition frequencies and radiation field strengths. This is a population-inversion analogy to self-induced transparency. Simulations of the inversion properties of' the modulated inversion pulse (MIP) are presented. It is shown that the inversion behavior can be explained by treating the MIP as a highly efficient adiabatic sweep. Criteria for establishing adiabaticity are discussed in detail. Finally, a method is presented for generating a sequence of phase-shifted radio-frequency pulses, from the continuously modulated pulse, which can be implemented on modern NMR and coherent optical spectrometers; experimental confirmation is given.